Thermodynamic Properties of Liquid Ag-Bi-Sn Alloys

被引:0
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作者
Zuoan Li
Sabine Knott
Adolf Mikula
机构
[1] Universität Wien,Institut für Anorganische Chemie/Materialchemie
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关键词
Silver-bismuth-tin; lead-free solders; liquid alloys; thermodynamic properties; electromotive force measurements;
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摘要
As a promising lead-free solder, the thermodynamic properties of the liquid ternary Ag-Bi-Sn system were investigated. Using an appropriate galvanic cell, the partial free energies of Sn in liquid Ag-Bi-Sn alloys were determined as a function of concentration and temperature. Thermodynamic properties were obtained for 27 alloys. Their composition was situated on three cross sections with the constant ratios of Ag:Bi = 2:1, 1:1, and 1:2. The integral Gibbs free energy and the integral enthalpy for the ternary system at 900 K were calculated by Gibbs–Duhem integration.
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页码:40 / 44
页数:4
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