Structural changes in copper(II) complexes with polyamine anion exchangers in the course of liquid-phase oxidation

被引：0
|
作者：
A. I. Kokorin
机构：
[1] Russian Academy of Sciences,N. N. Semenov Institute of Chemical Physics
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
copper, anion exchangers, complexes; structure; ESR spectra; oxidation reactions, catalysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In the course of liquid-phase catalytic oxidation, the coordination spheres and three-dimensional structures of the CuII complexes with various polyamine anion exchangers are changed. The main regularities of these changes were studied by ESR and IR spectroscopy. It was demonstrated that these transformations occur stepwise, which is associated with successive oxidation of the coordinated amino groups of the polymer-metal complexes in the reactions with the participation of molecular oxygen and hydrogen peroxide. The possible mechanisms of transformation of the metal complexes is discussed.
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页码：1730 / 1735
页数：5
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