N,N-diethylanilinium complex with borodicitric acid: Synthesis and crystal structure

被引：0
|
作者：
I. I. Zviedre
S. V. Belyakov
机构：
[1] Rīgas Tehniskā Universitāte,Neorganiskās Ķīmijas Institūts
[2] Latvijas Zinātņ u Akadēmija,Latvijas Organiskās Sintēzes Institūts
来源：
Russian Journal of Inorganic Chemistry | 2017年 / 62卷
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摘要：
N,N-Diethylanilinium dicitratoborate [C6H5NH(C2H5)2][(C6H6O7)2B] (I) has been synthesized for the first time. Single crystals has been synthesized in an aqueous solution to study the crystal structure of complex I by single-crystal X-ray diffraction. Crystals are triclinic, space group Р1 a = 9.6183(2) Å, b = 10.3153(3) Å, c = 13.7364(4) Å, α = 69.0304(12)°, β = 77.0394(13)°, γ = 89.5518(10)°, V = 1236.25(6) Å3, Z = 2, ρcalcd = 1.454 g/cm3. Structural units in a crystal of complex I are large complex dicitratoborate anions with a spirane structure and N,N-diethylanilinium cations. The crystal packing is a three-dimensional framework implemented via a system of hydrogen bonds like О–Н…О, О–Н…О, ОI, and N–Н…О.
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页码：665 / 670
页数：5
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