Qualitative quantum dynamics with allowance for Berry pseudorotation in XPF4 and PF5 molecules: II. The PF5 molecule

被引：0

作者：

A. V. Burenin

机构：

[1] Russian Academy of Sciences,Institute of Applied Physics

来源：

Optics and Spectroscopy | 2002年 / 92卷

关键词：

Invariant Subgroup; Basis Unit Vector; Vibronic State; Young Scheme; Identical Nucleus;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Based on the concept of the symmetry-group chain, a rigorous qualitative description of the internal quantum dynamics of the phosphorus pentafluoride molecule PF5 is constructed with allowance for its Berry pseudorotation transitions between twenty independent energetically equivalent equilibrium configurations.

引用

页码：45 / 52

页数：7

共 42 条

[41] CHEMISTRY IN FUMING NITRIC-ACIDS .1. NMR SPECTROSCOPIC STUDY OF PF5, HPO2F2 AND P4O10 IN THE SOLVENT SYSTEM 44WT-PERCENT N2O4 IN 100-PERCENT HNO3
ADDISON, CC
BAILEY, JW
BRUCE, SH
DOVE, MFA
HIBBERT, RC
LOGAN, N
POLYHEDRON, 1983, 2 (07) : 651 - 656
[42] REACTIONS OF S4N4 WITH SBCL5, SBF5, ASF5, PF5, AND HSO3F - PREPARATION AND CRYSTAL-STRUCTURES OF SALTS OF THE S4N42+ CATION - (S4N4)(SB3F14)(SBF6), (S4N4)(SO3F)2, (S4N4)(ASF6)2.SO2, (S4N4)(ALCL4)2, AND (S4N4)(SBCL6)2
GILLESPIE, RJ
KENT, JP
SAWYER, JF
SLIM, DR
TYRER, JD
INORGANIC CHEMISTRY, 1981, 20 (11) : 3799 - 3812

← 1 2 3 4 5 →