Crystal Structure of the Azido-Bridged Copper(II) Complex [Cu2L2(μ1,1-N3)2] Based on the 2-[(3-Amino-2,2-Dimethylpropylimino)-Methyl]-4-Bromophenol Schiff Base Ligand

被引：0

作者：

A. Ghaemi

B. Keyvani

K. Fayyazi

H. A. Rudbari

机构：

[1] Islamic Azad University,Department of Chemistry, Saveh Branch

[2] University of Isfahan,Department of Chemistry

来源：

Journal of Structural Chemistry | 2018年 / 59卷

关键词：

synthesis; Schiff base ligand; copper(II); crystal structure; 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol; azido-bridged; X-ray diffraction analysis;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

New end-on azido-bridged dinuclear copper(II) complex [Cu2L2(μ1,1-N3)2] (I) (HL = 2-[(3-amino-2,2-dimethylpropylimino)-methyl]-4-bromophenol) is synthesized and characterized by the elemental analysis and FT-IR spectroscopy. The crystal structure of I is determined by X-ray diffraction. The crystal of I is monoclinic, space group P21/c, a = 10.7926(4) Å, b = 12.4222(4) Å, c = 11.0894(4) Å, β = 100.085(2)°, V = 1463.76(9) Å3, Z = 2. The crystal structure shows that the structure contains [Cu2L2(μ1,1-N3)2] units joined together by intermolecular H-bonding interactions to form a 2D rectangular grid.

引用

页码：1176 / 1180

页数：4

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