Complexation in Water-Soluble Systems Poly-N-vinylpyrrolidone-Fullerene C60

被引:0
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作者
O. V. Ratnikova
E. Yu. Melenevskaya
M. V. Mokeev
V. N. Zgonnik
机构
[1] Russian Academy of Sciences,Institute of Macromolecular Compounds
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关键词
Fullerene; Ternary System; Additional Agent; Fullerene Content;
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摘要
Complexes of fullerene C60 with poly-N-vinylpyrrolidone were prepared by various procedures in the presence of additional agents in solution (systems C60-poly-N-vinylpyrrolidone and ternary system C60-tetraphenylporphyrin-poly-N-vinylpyrrolidone) and in the solid phase (C60-polyvinylpyrrolidone and C60-KBr-poly-N-vinylpyrrolidone). Formation of a donor-acceptor bond in the system C60-poly-N-vinylpyrrolidone was studied by 13C NMR. The conditions under which the ternary complex C60-tetraphenylporphyrin-poly-N-vinylpyrrolidone with fullerene content varied from 1 to 5 wt % can be obtained were found.
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页码:1620 / 1625
页数:5
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