Kinetics of the liquid-phase catalytic hydrogenation of chlorine-containing aromatic nitro compounds in the presence of pyridine

被引：0

作者：

V. G. Dorokhov

V. I. Savchenko

机构：

[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics

来源：

Kinetics and Catalysis | 2014年 / 55卷

关键词：

Pyridine; Nitro Compound; Apparent Rate Constant; Chloroaniline; Aromatic Nitro Compound;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

We have analyzed experimental kinetic data for nitro compound consumption, for the formation of the corresponding amino product, and for the accumulation of intermediate products and by-products in the hydrogenation of chlorine-containing aromatic nitro compounds. The reaction has been carried out under static conditions over a platinum catalyst on a porous support in the presence of pyridine. The effect of the admixture on different hydrogenation steps of a chlorine-containing aromatic nitro compound has been quantitatively interpreted.

引用

页码：446 / 455

页数：9

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