Kinetics of the liquid-phase catalytic hydrogenation of chlorine-containing aromatic nitro compounds in the presence of pyridine

被引：0
|
作者：
V. G. Dorokhov
V. I. Savchenko
机构：
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
来源：
Kinetics and Catalysis | 2014年 / 55卷
关键词：
Pyridine; Nitro Compound; Apparent Rate Constant; Chloroaniline; Aromatic Nitro Compound;
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学科分类号：
摘要：
We have analyzed experimental kinetic data for nitro compound consumption, for the formation of the corresponding amino product, and for the accumulation of intermediate products and by-products in the hydrogenation of chlorine-containing aromatic nitro compounds. The reaction has been carried out under static conditions over a platinum catalyst on a porous support in the presence of pyridine. The effect of the admixture on different hydrogenation steps of a chlorine-containing aromatic nitro compound has been quantitatively interpreted.
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页码：446 / 455
页数：9
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