Dielectric relaxation in polymers and copolymers of methacrylates and methacrylamides with chromophoric groups in side chains

The dielectric relaxation and molecular motion in polymers and copolymers of methacrylates and methacrylamides with π-conjugated anisodiametric chromophoric groups in the side chains are investigated in the temperature range from −170 to 120–150°C at frequencies of 0.1–100 kHz. It is shown that the motion of chromophoric groups and relaxation transitions in these systems are similar to those in liquid-crystal polymers with side mesogenic chains. The chromophoric groups execute orientational motion of two types: orientational rotations about the long axes in the glass state and orientational rotations about the short axes at temperatures above Tg. The π-conjugation excludes local motion within the chromophoric group.