Double Molecular Encapsulation of Tetrahydrofuran by an Amphiphilic Calix-[4]-arene

被引:0
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作者
Patrick Shahgaldian
Anthony W. Coleman
Beth Rather
Michael J. Zaworotko
机构
[1] CNRS UMR5086,Institut de Biologie et Chimie des Proteines
[2] University of South Florida,Department of Chemistry
关键词
amphiphilic; calix-[4]-arene; crystal structure; double inclusion; tetrahydrofuran;
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摘要
The crystal structure of para-octanoylcalix-[4]-arene·2 tetrahydrofuran complex reveals double inclusion of the guest molecules, one deep in the aromatic cavity and the other held in a four-fingered molecular hand formed by the aliphatic chains, the inclusion changes the molecular packing from a bilayer system in the absence of guest, to a head-to-tail antiparallel chain packing.
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页码:241 / 245
页数:4
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