CuInSe2 Formation by selenization of sequentially evaporated metallic layers

被引:53
|
作者
Caballero, R [1 ]
Guillén, C [1 ]
机构
[1] Dept Energias Renovables Ciemat, Madrid 28040, Spain
关键词
CuInSe2; Cu-In alloys; sequential evaporations;
D O I
10.1016/j.solmat.2004.05.019
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
CuInSe2 (CIS) thin films were grown by selenization of sequentially evaporated metallic precursors. Different types of sequential processes of evaporation have been tested: Cu/In/Cu/In, In/Cu/In/Cu and In/Cu/In. The selenization procedure was carried out within a partially closed graphite container. The CIS films showed single-phase chalcopyrite structure with preferential orientation in the (112) direction after 500degreesC selenization. The CIS surface morphology depended on the sequence used. The In/Cu/In seemed to be the best. An energy band gap above 0.95 eV and an absorption coefficient near 10(5) cm(-1) were obtained and similar optical properties were observed for all the prepared sequences. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:1 / 10
页数:10
相关论文
共 50 条
  • [21] SELENIZATION OF METALLIC CU-IN THIN-FILMS FOR CUINSE2 SOLAR-CELLS
    SZOT, J
    PRINZ, U
    JOURNAL OF APPLIED PHYSICS, 1989, 66 (12) : 6077 - 6083
  • [22] Structural properties of CuInSe2 films prepared by selenization of metallic precursors on MoNx film substrates
    Jiang, FD
    Zhang, L
    Feng, JY
    APPLIED SURFACE SCIENCE, 2006, 252 (08) : 3051 - 3057
  • [23] A NEW ELECTROCHEMICAL METHOD FOR SELENIZATION OF STACKED CUIN LAYERS AND PREPARATION OF CUINSE2 BY THERMAL ANNEALING
    FRITZ, HP
    CHATZIAGORASTOU, P
    THIN SOLID FILMS, 1994, 247 (01) : 129 - 133
  • [24] Characteristics of CuInSe2 thin films grown by the selenization method
    Kim, SD
    Kim, HJ
    Adurodija, FO
    Yoon, KH
    Song, JS
    JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 1999, 35 : S403 - S405
  • [25] Raman spectroscopy of CuInSe2 thin films prepared by selenization
    Zaretskaya, EP
    Gremenok, VF
    Riede, V
    Schmitz, W
    Bente, K
    Zalesski, VB
    Ermakov, O
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2003, 64 (9-10) : 1989 - 1993
  • [26] CuInSe2 thin films formed by selenization of Cu–In precursors
    M.E Calixto
    P.J Sebastian
    Journal of Materials Science, 1998, 33 : 339 - 345
  • [27] Effect of Cu/In ratio on properties of CuInSe2 thin films prepared by selenization of Cu-In layers
    Shi, Jen-Bin
    Chen, Yu-Cheng
    Wu, Po-Feng
    Yang, Shui-Yuang
    Kang, Tsung-Kuei
    Yang, Ping-Chang
    Lin, Cheng-Li
    Young, San-Lin
    Kao, Ming-Cheng
    CRYSTAL RESEARCH AND TECHNOLOGY, 2013, 48 (02) : 94 - 99
  • [28] EPITAXIAL LAYERS OF CUINSE2 ON GAAS
    SCHUMANN, B
    GEORGI, C
    TEMPEL, A
    KUHN, G
    VANNAM, N
    NEUMANN, H
    HORIG, W
    THIN SOLID FILMS, 1978, 52 (01) : 45 - 52
  • [29] METHOD OF THE SELENIZATION OF LIQUID CU-IN ALLOY FOR THE SYNTHESIS OF CUINSE2
    NOMURA, S
    TAKIZAWA, T
    KUDO, T
    NAGATA, Y
    MOUNAI, T
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1991, 30 (12A): : 3341 - 3343
  • [30] PREPARATION OF CUINSE2 FILMS BY SELENIZATION OF CUIN PRECURSOR IN VACUUM CHAMBER
    GUPTA, A
    OHNO, T
    KARIYA, T
    SHIRAKATA, S
    ISOMURA, S
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 1993, 32 : 74 - 76