Synthesis and X-ray crystal structure of an anionic heteronuclear metallamacrocyclic triangle

被引：33
|
作者：
Vicente, J
Chicote, MT
Alvarez-Falcón, MM
Jones, PG
机构：
[1] Univ Murcia, Dept Quim Inorgan, Grp Quim Organomet, E-30071 Murcia, Spain
[2] Tech Univ Braunschweig, Inst Anorgan & Analyt Chem, D-38023 Braunschweig, Germany
来源：
CHEMICAL COMMUNICATIONS | 2004年 / 23期
关键词：
D O I：
10.1039/b409921d
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
trans-[Pt{C=C(Ar)C-CH}(2)(PMe3)(2)] (Ar = C6Me4-3,4,5,6) (1) reacts with PPN[Au(acac)(2)] (Hacac = acetylacetone; 1:1.16 molar ratio; PPN = (Ph3P)(2)N) to give PPN[{Au-{Pt(PMe3)(2)}(2)}{mu-Ar(C=C)(2)}(3)] (2) the crystal structure of which showed the anions as quasi equilateral triangles stacked parallel to each other through C-H...Au interactions, resulting in channels of rhombic cross-section.
引用
收藏
页码：2658 / 2659
页数：2
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