Development and Research on Ion-Conducting Membranes Based on Cross-Linked Polyvinyl Alcohol

被引：2
|
作者：
Lyozova, O. S. [1 ]
Zagrebelny, O. A. [1 ]
Krasnopeeva, E. L. [1 ,2 ]
Baranchikov, A. S. [3 ]
Shilova, O. A. [1 ]
Ivanova, A. G. [1 ]
机构：
[1] Russian Acad Sci, Grebenshchikov Inst Silicate Chem, St Petersburg 199034, Russia
[2] Russian Acad Sci, Inst Macromol Cpds, St Petersburg 199004, Russia
[3] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia
来源：
GLASS PHYSICS AND CHEMISTRY | 2021年 / 47卷 / 02期
关键词：
hybrid electrolytic membrane; cross-linked polyvinyl alcohol; furfural; sol-gel method; aminosulfonic acid; tetraethoxysilane; ionic conductivity; degree of swelling in water; POLY(VINYL; SURFACE; SILICA; ACID; PVA;
D O I：
10.1134/S1087659621020061
中图分类号：
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号：
0805 ; 080502 ;
摘要：
Membranes based on polyvinyl alcohol crosslinked with furfural, both unmodified and modified with aminosulfonic acid with and without tetraethoxysilane (TEOS), and membranes not crosslinked with furfural but modified with aminosulfonic acid are obtained and studied. The composition, surface morphology, degree of swelling in water, and specific electrical conductivity are studied. It is found that an electrolytic membrane based on polyvinyl alcohol crosslinked with furfural modified with tetraethoxysilane and aminosulfonic acid has the highest specific electrical conductivity (2.35 x 10(-2) S/cm at a temperature of 95 degrees C) and a wider range of temperature stability (20-160 degrees C) in comparison with other obtained membranes based on polyvinyl alcohol and the reference membrane Nafion-115. It is determined that the degree of swelling of the developed membranes is rather high in comparison with the reference membrane Nafion-115.
引用
收藏
页码：173 / 180
页数：8
相关论文
共 50 条
  • [41] SWELLING OF CROSS-LINKED POLYVINYL-ALCOHOL IN SOLVENTS OF DIFFERENT NATURE
    KUZNETSOVA, VA
    SOROKIN, AY
    GANDELSMAN, MI
    BUDTOV, VP
    VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A, 1990, 32 (04): : 738 - 743
  • [42] Properties enhancement of magnesium phosphate cement by cross-linked polyvinyl alcohol
    Zarybnicka, Lucie
    Macova, Petra
    Viani, Alberto
    CERAMICS INTERNATIONAL, 2022, 48 (02) : 1947 - 1955
  • [43] Functionalised cross-linked polyvinyl alcohol as new matrix for lipase immobilization
    Cernia, E
    Milana, G
    Ortaggi, G
    Palocci, C
    Soro, S
    STABILITY AND STABILIZATION OF BIOCATALYSTS, 1998, 15 : 667 - 671
  • [44] Wound healing potential of curcumin cross-linked chitosan/ polyvinyl alcohol
    Abbas, Mazhar
    Hussain, Tariq
    Arshad, Muhammad
    Ansari, Abdur Rahman
    Irshad, Asma
    Nisar, Jan
    Hussain, Fida
    Masood, Nasir
    Nazir, Arif
    Iqbal, Munawar
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2019, 140 : 871 - 876
  • [45] Synthesis, Characterization and Application of Disodium Tetraborate Cross-Linked Polyvinyl Alcohol Membranes for Pervaporation Dehydration of Ethylene Glycol
    Dave, Haresh K.
    Nath, Kaushik
    ACTA CHIMICA SLOVENICA, 2018, 65 (04) : 902 - 918
  • [46] Research progress of cross-linked fiber membranes for lithium-ion battery separators
    Deng, Jianhui
    Xie, Jiekai
    Zhang, Guoqing
    Yang, Xiaoqing
    CHEMICAL ENGINEERING SCIENCE, 2023, 280
  • [47] Preparation and Photochromic Properties of Nanocomposites Based on Chemically Cross-Linked Polyvinyl Alcohol and Phosphotungstic Acid
    Tretinnikov, O. N.
    Sushko, N. I.
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (12) : 2177 - 2182
  • [48] Preparation and photochromic properties of nanocomposites based on chemically cross-linked polyvinyl alcohol and phosphotungstic acid
    O. N. Tretinnikov
    N. I. Sushko
    Russian Journal of Physical Chemistry A, 2011, 85 : 2177 - 2182
  • [49] Preparation and characterization of ionically cross-linked proton-conducting membranes
    Tang, CM
    Zhang, W
    Kerres, J
    JOURNAL OF NEW MATERIALS FOR ELECTROCHEMICAL SYSTEMS, 2004, 7 (04) : 287 - 298
  • [50] Cross-linked Single-Ion Solid Polymer Electrolytes with Alternately Distributed Lithium Sources and Ion-Conducting Segments for Lithium Metal Batteries
    Chen, Shaoshan
    Li, Yu
    Wang, Yong
    Li, Zeyu
    Peng, Cong
    Feng, Yiyu
    Feng, Wei
    MACROMOLECULES, 2021, 54 (19) : 9135 - 9144
12345