Eased on first-principles calculations and analysis of x-ray absorption measurements, an unconventional mechanism is proposed for the saturation of carriers in highly it-doped Si. The mechanism is Fermi-level pinning from a new class of defect centers containing two separated but interacting dopant atoms with no associated Si vacancies. The number of such centers increases sharply at high doping levels. A simple model provides very good agreement with the maximum carrier concentrations observed, in Si.
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CEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
CEA INAC Grenoble, UMR E CEA UJF Grenoble 1, SiNaPS Lab SP2M, F-38054 Grenoble, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Thissandier, Fleur
Gentile, Pascal
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CEA INAC Grenoble, UMR E CEA UJF Grenoble 1, SiNaPS Lab SP2M, F-38054 Grenoble, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Gentile, Pascal
Pauc, Nicolas
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CEA INAC Grenoble, UMR E CEA UJF Grenoble 1, SiNaPS Lab SP2M, F-38054 Grenoble, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Pauc, Nicolas
Hadji, Emmanuel
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CEA INAC Grenoble, UMR E CEA UJF Grenoble 1, SiNaPS Lab SP2M, F-38054 Grenoble, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Hadji, Emmanuel
Le Comte, Annaig
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CEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, F-44322 Nantes 3, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Le Comte, Annaig
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Crosnier, Olivier
Bidan, Gerard
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CEA INAC Grenoble, INAC Dir, F-38054 Grenoble, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Bidan, Gerard
Sadki, Said
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CEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France
Sadki, Said
Brousse, Thierry
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Univ Nantes, CNRS, Inst Mat Jean Rouxel IMN, F-44322 Nantes 3, FranceCEA INAC Grenoble, LEMOH SPrAM UMR 5819, CEA, CNRS,UJF, F-38054 Grenoble, France