Preparation of alcohols from sulfones and trialkylboranes

被引：7
|
作者：
Billaud, C
Goddard, JP
Le Gall, T
Mioskowski, C
机构：
[1] CEA Saclay, Serv Marquage Mol & Chim Bioorgan, F-91191 Gif Sur Yvette, France
[2] Univ Strasbourg 1, Fac Pharm, CNRS, UMR 7514,Lab Synthese Bioorgan, F-67401 Illkirch Graffenstaden, France
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 24期
关键词：
sulfone; borane; boron compound; alcohol;
D O I：
10.1016/S0040-4039(03)01025-6
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of Sulfone anions with trialkylboranes followed by thermal isomerization of the obtained boron compounds in the presence of excess borane-methyl sulfide complex and by alkaline hydroperoxide oxidation yields primary alcohols. (C) 2003 Elsevier Science Ltd. All rights reserved.
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页码：4451 / 4454
页数：4
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