Co-MOF Nanosheet Arrays for Efficient Alkaline Oxygen Evolution Electrocatalysis

被引:41
|
作者
Yu, Jin [1 ]
Cao, Yang [2 ]
Liu, Qian [3 ]
Luo, Yonglan [3 ]
Liu, Yang [4 ]
Shi, Xifeng [5 ]
Asiri, Abdullah M. [6 ,7 ]
Li, Tingshuai [1 ]
Sun, Xuping [2 ]
机构
[1] Univ Elect Sci & Technol China, Sch Mat & Energy, Chengdu 611731, Sichuan, Peoples R China
[2] Univ Elect Sci & Technol China, Inst Fundamental & Frontier Sci, Chengdu 610054, Sichuan, Peoples R China
[3] Chengdu Univ, Inst Adv Study, Chengdu 610106, Sichuan, Peoples R China
[4] Henan Normal Univ, Sch Mat Sci & Engn, Xinxiang 453007, Henan, Peoples R China
[5] Shandong Normal Univ, Coll Chem Chem Engn & Mat Sci, Jinan 250014, Shandong, Peoples R China
[6] King Abdulaziz Univ, Fac Sci, Dept Chem, POB 80203, Jeddah 21589, Saudi Arabia
[7] King Abdulaziz Univ, Ctr Excellence Adv Mat Res, POB 80203, Jeddah 21589, Saudi Arabia
关键词
Co-MOF nanosheet arrays; nickel foam; water oxidation; alkaline reaction; WATER OXIDATION ELECTROCATALYSIS; METAL-ORGANIC FRAMEWORK; BIFUNCTIONAL ELECTROCATALYST; NANOWIRE ARRAY; NI FOAM;
D O I
10.1002/cnma.202100153
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
It's highly desirable to devise and develop non-precious metal catalysts for efficient water oxidation catalysis in alkaline solution. Herein, we report Co-MOF nanosheet arrays grown on the three dimensional conductive nickel foam (Co-MOF/NF) through a hydro-thermal process for efficient alkaline oxygen evolution electrocatalysis. Such catalyst displays an excellent electrochemical performance by achieving an overpotential of 290 mV at 20 mA cm(-2) in 1.0 M KOH. Besides, it possesses both a good electrochemical stability and a high turnover frequency of 0.14 s(-1) at the overpotential of 400 mV.
引用
收藏
页码:906 / 909
页数:4
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