Extraction study of uranium(VI) and thorium(IV) salicylates with triphenylarsine oxide

被引:11
|
作者
Patil, NN [1 ]
Shinde, VM [1 ]
机构
[1] Inst Sci, Anal Lab, Bombay 400032, Maharashtra, India
关键词
D O I
10.1007/BF02034240
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Triphenylarsine oxide is proposed as an extractant for the solvent extraction of uranium and thorium salicylates. ?he optimum extraction conditions an: established by studying the various parameters such as pH, sodium salicylate concentration, triphenylarsine oxide concentration, diluents and shaking time. The probable extracted species as ascertained by log D-log C plots are UO2(Hsal)(2) . 2TPAsO and Th(Hsal)(4) . 2TPAsO. The method is simple, fast, precise and permits the determination of uranium and thorium in monazite sand samples.
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页码:21 / 24
页数:4
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