Synthesis and spectroscopic investigation of some iron(III) complexes

被引：0
|
作者：
Singh, B [1 ]
Sahai, P [1 ]
机构：
[1] Banaras Hindu Univ, Fac Sci, Dept Chem, Varanasi 221005, Uttar Pradesh, India
来源：
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY | 1998年 / 28卷 / 04期
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D O I：
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中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The chelating behaviour of neutral and deprotonated (anionic) 2-acetylthiophene-2-furoylhydrazone (Hatfh), 2-acetylfuran-2-furoylhydrazone (Haffh), 2-acetylpyridine-2-furoylhydrazone (Hapfh) and Omega-hydroxyacetophenone-2-furoylhydrazone (H(2)hafh) has been investigated in the complexs of iron(III). The hydrazones react with ferric chloride to yield complexes of the types [Fe(HL)Cl-2(OH)] [HL = Hatfh, Hapfh], Fe(Hatfh)(2)Cl-2(OH) Fe(Hhafh)Cl-2(H2O), Fe-2(L-3)(OH)(3)(H2O) HL = Hatfh, Haffh, Hapfh] and Fe(Hhafh)(3). The complexes have been characterized by elemental analysis, molar conductance, magnetic susceptibility, electronic, infrared and Mossbauer spectral studies and their stereochemistries are discussed.
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页码：587 / 601
页数：15
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