Palladium-catalyzed desulfitative cross-coupling of arylsulfinates with arylboronic acids

被引：27

作者：

Cheng, Kai ^{[1
]}

Yu, Hai-Zhu ^{[2
]}

Zhao, Baoli ^{[1
]}

Hu, Sai ^{[3
]}

Zhang, Xian-Man ^{[1
]}

Qi, Chenze ^{[1
]}

机构：

[1] Shaoxing Univ, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China

[2] Univ Sci & Technol Beijing, Dept Polymer Sci & Engn, Beijing 100083, Peoples R China

[3] Ningbo Univ, Coll Mat Sci & Chem Engn, Ningbo 310014, Zhejiang, Peoples R China

来源：

RSC ADVANCES | 2014年 / 4卷 / 101期

基金：

中国国家自然科学基金;

关键词：

SUZUKI-MIYAURA REACTION; ARYL SULFINIC ACIDS; DIRECT ESI-MS; ARENESULFONYL CHLORIDES; BOND FORMATION; DECARBOXYLATIVE PALLADATION; ARYLSULFONYL CHLORIDES; SULFONYL CHLORIDES; ALKENYL PHOSPHATES; CARBOXYLIC-ACIDS;

D O I：

10.1039/c4ra07455f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Palladium (Pd)-catalyzed desulfitative cross-coupling reactions of sodium arylsulfinates with a wide variety of arylboronic acids were achieved in good to excellent yields under simple aerobic conditions. These catalytic reactions could be accelerated by addition of a catalytic amount of Cu(II) salts as co-catalyst. Moreover, these reactions were tolerant to all of the tested functional groups, making them attractive alternatives to the traditional cross-coupling reactions.

引用

页码：57923 / 57928

页数：6

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