A novel strategy for two-photon holographic recording:: Stepwise two-photon absorption of α-quinquethiophene followed by energy transfer to an aryl azide

被引:12
|
作者
Shimizu, Masaki [1 ]
Schelper, Michael
Mochida, Kenji
Hiyama, Tamejiro
Adachi, Masafumi
Sasaki, Yutaka
Akiyama, Seiji
Maeda, Shuuichi
Kanbara, Hirohisa
Mori, Yuhei
Kurihara, Takashi
机构
[1] Kyoto Univ Katsura, Grad Sch Engn, Dept Chem Mat, Nishikyo Ku, Kyoto 6158510, Japan
[2] Sci & Technol Res Ctr Inc, Mitsubishi Chem Grp, Aoba Ku, Yokohama, Kanagawa 2278502, Japan
[3] NTT Corp, NTT Photon Lab, Atsugi, Kanagawa 2430198, Japan
关键词
D O I
10.1002/adma.200700432
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An efficient method for two-photon holographic recording is demonstrated. Two-photon absorption from gate and holographic lights is effected by silicon-terminated alpha-quinquethiophene, and data recording is achieved by a coexisting 3,3'-diazidodiphenyl sulfone (see figure). The efficiency of the thiophene-azide system is at least two orders of magnitude higher than that of a biacetyl-based system.
引用
收藏
页码:1826 / +
页数:5
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