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Fusion of C60 with cyclic amino acid and thiourea by hetero Diels-Alder reactions
被引:0
|作者:
Ohno, M
[1
]
Kojima, S
[1
]
Shirakawa, Y
[1
]
Eguchi, S
[1
]
机构:
[1] Nagoya Univ, Grad Sch Engn, Dept Mol Design & Engn, Chikusa Ku, Nagoya, Aichi 46401, Japan
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D O I:
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中图分类号:
O62 [有机化学];
学科分类号:
070303 ;
081704 ;
摘要:
C-60 underwent hetero Diels-Alder reaction with a carbethoxy-substituted 2-aza-1,3-butadiene and trimethylsilylthio-substituted 1,3-diaza-1,3-butadiene (which possibly reacts as trimethylsilylamino-substituted 1-thia-3-aza-1,3-butadiene) to give C-60 derivatives fused with cyclic amino acid and thiourea, respectively. The latter was explained to arise under equilibrated conditions.
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页码:49 / 52
页数:4
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