Concerted Diels-Alder reaction between anthracene and C60

被引：18
|
作者：
Chronakis, N [1 ]
Orfanopoulos, M [1 ]
机构：
[1] Univ Crete, Dept Chem, Iraklion 71409, Crete, Greece
来源：
TETRAHEDRON LETTERS | 2001年 / 42卷 / 06期
关键词：
fullerenes; 4+2] cycloaddition; isotope effects; hyperconjugation;
D O I：
10.1016/S0040-4039(00)02211-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The Diels-Alder reaction of anthracene with C-60 has been investigated experimentally by using secondary isotope effects. The inverse alpha -secondary isotope effect in conjunction with the unity value of the P-secondary isotope effect indicates a concerted mechanism for the title reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：1201 / 1204
页数：4
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