Isobaric Vapor-Liquid Equilibria for Binary Mixtures of 2-Phenylethanol with 1-Phenylethanol, 2-Phenylpropan-2-ol, Ethylbenzene, and Isopropylbenzene at 101.3 kPa

被引：6
|
作者：
Das, Sudip [1 ]
Ghosh, Shashwata [2 ]
Nadeem, Mohd [1 ]
Seethamraju, Srinivas [2 ]
Mahajani, Sanjay [1 ]
机构：
[1] Indian Inst Technol, Dept Chem Engn, Mumbai 400076, Maharashtra, India
[2] Indian Inst Technol, Dept Energy Sci & Engn, Mumbai 400076, Maharashtra, India
来源：
JOURNAL OF CHEMICAL AND ENGINEERING DATA | 2021年 / 66卷 / 04期
关键词：
Maximum likelihood estimation - Testing - Liquids - Ethylbenzene;
D O I：
10.1021/acs.jced.0c01040
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
The isobaric binary vapor-liquid equilibrium (VLE) data for the mixture of 2-phenylethanol (2PEA) with 1-phenylethanol (1PEA), 2-phenylpropan-2ol (2P2P), ethylbenzene (ETB), and isopropylbenzene (IPB) is generated at 101.3 kPa. The Fredenslund test and Redlich-Kister area test methods were used to confirm the consistency of the measured VLE experimental data. Subsequently, the data sets are correlated by the nonrandom two-liquid (NRTL) and universal quasi-chemical (UNIQUAC) thermodynamic models, and the binary interaction parameters for the two models were estimated using the Britt-Luecke algorithm and the maximum likelihood objective function. The estimation was found to be good for both the activity coefficient models.
引用
收藏
页码：1754 / 1762
页数：9
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