Formic acid catalyzed one-pot synthesis of α-aminophosphonates: an efficient, inexpensive and environmental friendly organocatalyst

被引：1
|
作者：
Mehraban, Jamshid Azarnia [1 ]
Jalali, Mahsa Sadat [1 ]
Heydari, Akbar [1 ]
机构：
[1] Tarbiat Modares Univ, Chem Dept, Tehran, Iran
来源：
CHEMICAL PAPERS | 2018年 / 72卷 / 09期
关键词：
alpha-Aminophosphonates; Formic acid; Organocatalyst; Kabachnik-Fields reaction; KABACHNIK-FIELDS REACTION; AMINO PHOSPHONATES; SOLVENT-FREE; BIOLOGICAL-ACTIVITY; DIASTEREOSELECTIVE SYNTHESIS; MULTICOMPONENT SYNTHESIS; 3-COMPONENT SYNTHESIS; REUSABLE CATALYST; HYDROGEN STORAGE; FACILE SYNTHESIS;
D O I：
10.1007/s11696-018-0434-6
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Aqueous formic acid is used for the synthesis of alpha-aminophosphonates through Kabachnik-Fields reaction applying aromatic amine, phosphite, and carbonyl compounds. Using formic acid as an efficient and low-cost organocatalyst provides environmental friendly, high yields, low reaction time and mild reaction condition. The isolated products were analyzed by IR, NMR, and mass techniques. [GRAPHICS] .
引用
收藏
页码：2215 / 2223
页数：9
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