Ni/NHC-catalyzed cross-coupling of methyl sulfinates and amines for direct access to sulfinamides

被引：11

作者：

Li, Gang-Jian ^{[1
]}

Pan, You-Lu ^{[1
]}

Liu, Yan-Ling ^{[1
]}

Xu, Hai-Feng ^{[1
]}

Chen, Jian-Zhong ^{[1
]}

机构：

[1] Zhejiang Univ, Coll Pharmaceut Sci, 866 Yuhangtang Rd, Hangzhou, Zhejiang, Peoples R China

来源：

TETRAHEDRON LETTERS | 2019年 / 60卷 / 46期

基金：

中国国家自然科学基金;

关键词：

Sulfinamide; Ni/NHC; Cross-coupling; Methyl sulfinates; ASYMMETRIC-SYNTHESIS; COMPLEXES;

D O I：

10.1016/j.tetlet.2019.151260

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It was reported to develop a simple and convenient method for the Ni/NHC-catalyzed cross-coupling of methyl sulfinates and amines without an acid/base to afford secondary or tertiary sulfinamides in moderate to good yields. The method can provide the desired products with broad substrate scope, good chemoselectivity and good functional group compatibility. The presented approach may enrich the Nil NHC catalyst system and promote the applications of methyl sulfinates in the organic sulfur chemistry. (C) 2019 Elsevier Ltd. All rights reserved.

引用

页数：5

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