Pattern formation at the nematic smectic-B interface

被引:4
|
作者
Tóth-Katona, T [1 ]
Börzsönyi, T [1 ]
Buka, A [1 ]
机构
[1] Hungarian Acad Sci, Res Inst Solid State Phys & Opt, H-1525 Budapest, Hungary
关键词
pattern formation; phase transition; liquid crystals;
D O I
10.1080/10587250008031042
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Free growth properties of the smectic B liquid crystalline phase into the supercooled nematic have been investigated in quasi-twodimensional geometry. Different orientation combinations of the two phases have been achieved experimentally and the interfacial patterns have been studied and analysed as a function of undercooling. The angular dependence of the surface tension has been deduced From the shape of the interface in thermal equilibrium The experimentally determined surface tension anisotropy has been incorporated into computer simulations based on the phase-field model. The simulations have reproduced qualitatively the rich variety of morphologies observed in the experiments for a given set of undercoolings in three geometries. Anisotropic heat diffusion on the nematic side, relevant to our experimental system has also been introduced. Both in the experiments and in the simulations we find that the growth is faster in the lower heat diffusion direction.
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页码:175 / 208
页数:34
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