Carbonate phobic (Zn,Mn)-Al hydrotalcite-like compounds

被引：25
|
作者：
Sampieri, Alvaro
Fetter, Geolar
Pfeiffer, Heriberto
Bosch, Pedro
机构：
[1] Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico
[2] Univ Autonoma Puebla, Fac Ciencias Quim, Puebla 72570, Mexico
来源：
SOLID STATE SCIENCES | 2007年 / 9卷 / 05期
关键词：
hydrotalcite-like compounds; MnO4-; incorporation; CO2; sorption; electronegativity; microwave irradiation;
D O I：
10.1016/j.solidstatesciences.2007.03.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis method of three series of nitrated (Zn,Mn)-Al hydrotalcites in the presence of microwave irradiation is presented. MnO4- anions were partially incorporated between the layers of those compounds and a staged intercalation occurred. In the presence Of CO2, nitrated and permanganate intercalated hydrotalcites were tested in CO32- retention. Carbonate phobic character was observed and it may be correlated to 3 the poor basicity of hydrotalcites, thus, to the electronegativity of M2+ cations. (c) 2007 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：394 / 403
页数：10
相关论文
共 50 条
  • [41] Thermal decomposition study of hydrotalcite-like compounds
    Nebot-Díaz, I
    Rives, V
    Rocha, J
    Carda, JB
    BOLETIN DE LA SOCIEDAD ESPANOLA DE CERAMICA Y VIDRIO, 2002, 41 (04): : 411 - 414
  • [42] Synthesis and catalytic performance of Fe-Mg-Al Hydrotalcite-like compounds
    Zhu Hongtao
    Ge Hongyu
    Jiao Shouchang
    ENVIRONMENTAL ENGINEERING, PTS 1-4, 2014, 864-867 : 679 - 683
  • [43] Fabrication of porous microspheres and network arrays of Zn-Al hydrotalcite-like compounds on Al substrate via facile hydrothermal method
    Shi, Rubda
    Yang, Ping
    Yin, Yunyu
    Dong, Xiaobin
    Li, Jia
    CERAMICS INTERNATIONAL, 2014, 40 (05) : 6855 - 6863
  • [44] On the Acid-Base Properties of Microwave Irradiated Hydrotalcite-like Compounds Containing Zn2+ and Mn2+
    Sampieri, Alvaro
    Lima, Enrique
    LANGMUIR, 2009, 25 (06) : 3634 - 3639
  • [45] Rheological properties of hydrotalcite-like compounds/montmorillonite suspensions
    Li, Shu-Ping
    Liu, Ke
    COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2007, 304 (1-3) : 14 - 17
  • [46] Prediction of thermodynamic data for hydrotalcite-like compounds.
    Allada, RK
    Navrotsky, A
    Casey, WH
    Berbeco, HT
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 223 : U615 - U615
  • [47] ANION-EXCHANGE PROPERTIES OF HYDROTALCITE-LIKE COMPOUNDS
    MIYATA, S
    CLAYS AND CLAY MINERALS, 1983, 31 (04) : 305 - 311
  • [48] SYNTHESIS OF NEW HYDROTALCITE-LIKE COMPOUNDS AND THEIR PHYSICOCHEMICAL PROPERTIES
    MIYATA, S
    KUMURA, T
    CHEMISTRY LETTERS, 1973, (08) : 843 - 848
  • [49] Bacterial Cellulose as a Template for Preparation of Hydrotalcite-Like Compounds
    Perotti, Gustavo F.
    Barud, Hernane S.
    Ribeiro, Sidney J. L.
    Constantino, Vera R. L.
    JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY, 2014, 25 (09) : 1647 - 1655
  • [50] Preparation and application of Cu/Cr hydrotalcite-like compounds
    Qingze Jiao
    Hongbo Liu
    Yun Zhao
    Zhe Zhang
    Journal of Materials Science, 2009, 44 : 4422 - 4428
12345