Carbonate phobic (Zn,Mn)-Al hydrotalcite-like compounds

被引：25
|
作者：
Sampieri, Alvaro
Fetter, Geolar
Pfeiffer, Heriberto
Bosch, Pedro
机构：
[1] Univ Nacl Autonoma Mexico, Inst Invest Mat, Mexico City 04510, DF, Mexico
[2] Univ Autonoma Puebla, Fac Ciencias Quim, Puebla 72570, Mexico
来源：
SOLID STATE SCIENCES | 2007年 / 9卷 / 05期
关键词：
hydrotalcite-like compounds; MnO4-; incorporation; CO2; sorption; electronegativity; microwave irradiation;
D O I：
10.1016/j.solidstatesciences.2007.03.014
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis method of three series of nitrated (Zn,Mn)-Al hydrotalcites in the presence of microwave irradiation is presented. MnO4- anions were partially incorporated between the layers of those compounds and a staged intercalation occurred. In the presence Of CO2, nitrated and permanganate intercalated hydrotalcites were tested in CO32- retention. Carbonate phobic character was observed and it may be correlated to 3 the poor basicity of hydrotalcites, thus, to the electronegativity of M2+ cations. (c) 2007 Elsevier Masson SAS. All rights reserved.
引用
收藏
页码：394 / 403
页数：10
相关论文
共 50 条
  • [1] CO2 capture by Mg–Al and Zn–Al hydrotalcite-like compounds
    Thiago M. Rossi
    Juacyara C. Campos
    Mariana M. V. M. Souza
    Adsorption, 2016, 22 : 151 - 158
  • [2] PREPARATION AND CHARACTERIZATION OF AL-RICH ZN-AL HYDROTALCITE-LIKE COMPOUNDS
    THEVENOT, F
    SZYMANSKI, R
    CHAUMETTE, P
    CLAYS AND CLAY MINERALS, 1989, 37 (05) : 396 - 402
  • [3] Zn-Al-La hydrotalcite-like compounds as heating stabilizer in PVC resin
    温润娟
    杨占红
    陈红燕
    胡友旺
    段吉安
    JournalofRareEarths, 2012, 30 (09) : 895 - 902
  • [4] Zn-Al-La hydrotalcite-like compounds as heating stabilizer in PVC resin
    Wen Runjuan
    Yang Zhanhong
    Chen Hongyan
    Hu Youwang
    Duan Ji'an
    JOURNAL OF RARE EARTHS, 2012, 30 (09) : 895 - 902
  • [5] SYNTHESIS AND PROPERTIES OF MG-ZN-AL-SO4 HYDROTALCITE-LIKE COMPOUNDS
    KOOLI, F
    KOSUGE, K
    HIBINO, T
    TSUNASHIMA, A
    JOURNAL OF MATERIALS SCIENCE, 1993, 28 (10) : 2769 - 2773
  • [6] CO2 capture by Mg-Al and Zn-Al hydrotalcite-like compounds
    Rossi, Thiago M.
    Campos, Juacyara C.
    Souza, Mariana M. V. M.
    ADSORPTION-JOURNAL OF THE INTERNATIONAL ADSORPTION SOCIETY, 2016, 22 (02): : 151 - 158
  • [7] Intercalation of diclofenac in modified Zn/Al hydrotalcite-like preparation
    Heraldy, E.
    Suprihatin, R. W.
    Pranoto
    10TH JOINT CONFERENCE ON CHEMISTRY, 2016, 107
  • [8] Effect of permanent charge on the intrinsic ionization constant of Zn-Al hydrotalcite-like compounds
    Li, LF
    Hou, WG
    Jiao, YN
    Liu, CX
    ACTA PHYSICO-CHIMICA SINICA, 2004, 20 (05) : 459 - 462
  • [9] Enhanced NOx adsorption using calcined Zn/Mg/Ni/Al hydrotalcite-like compounds
    Ni, Zheming
    Chen, Aimin
    Fang, Caiping
    Wang, Ligeng
    Yu, Weihua
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2009, 70 (3-4) : 632 - 638
  • [10] M-Mn-Al hydrotalcite-like compounds as precursors for methyl benzoate hydrogenation catalysts
    Chen, AM
    Xu, HL
    Yue, YH
    Shen, W
    Hua, WM
    Gao, Z
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (20) : 6409 - 6415
12345