New synthesis of trimethylsilyl esters of phosphorus(III) acids

被引：3

作者：

Morgalyuk, Vasily ^{[1
]}

Strelkova, Tatyana ^{[1
]}

Brel, Valery ^{[1
]}

机构：

[1] Russian Acad Sci, Nesmeyanov Inst Organoelement Cpds, Ul Vavilova 28, Moscow 119991, Russia

来源：

MONATSHEFTE FUR CHEMIE | 2019年 / 150卷 / 11期

关键词：

Phosphorus(III) trimethylsilylether; Phosphorus compounds; Reaction mechanisms; Retro reactions; REARRANGEMENT; REACTIVITY;

D O I：

10.1007/s00706-019-02511-6

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A novel synthetically important reaction has been developed for the quick, convenient, and high-yield preparation of trimethylsilyl esters of phosphorus(III) acids, synthetically valuable Michaelis-Arbuzov reaction precursors. Commercially and synthetically available initial compounds used are derivatives of propan-2-ol phosphorylated in the second position capable of long-term storage and available silylating reagents: hexamethyldisilazane, bis(trimethylsilyl)acetamide, and diethyl(trimethylsilyl)amine. Also, a stepwise reaction scheme of the starting compounds with silylating reagents has been proposed. [GRAPHICS]

引用

页码：1993 / 1997

页数：5

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