Nickel-Catalyzed Direct C-H Arylation and Alkenylation of Heteroarenes with Organosilicon Reagents

被引：243
|
作者：
Hachiya, Hitoshi [1 ]
Hirano, Koji [1 ]
Satoh, Tetsuya [1 ]
Miura, Masahiro [1 ]
机构：
[1] Osaka Univ, Dept Appl Chem, Fac Engn, Suita, Osaka 5650871, Japan
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 12期
关键词：
alkenylation; arylation; heterocycles; nickel; silanes; CROSS-COUPLING REACTIONS; MEDIATED DIRECT ARYLATION; ARYL BOND FORMATION; CARBON-HYDROGEN; REGIOSELECTIVE ARYLATION; DIRECT ALKYNYLATION; ARYLBORONIC ACIDS; AROMATIC KETONES; ROOM-TEMPERATURE; SILYL MIGRATION;
D O I：
10.1002/anie.200906996
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
"Chemical Equation Presented" Breaking the Si-lence: The direct crosscoupling of heteroarenes with aryl- or alkenylsilanes proceeds efficiently, in the presence of a nickel catalyst, to create a wide range of aryl- and alkenyl-heteroaryl bonds efficiently (see scheme; DMAc= N.N-dimethylacetamide, bpy = 2,2′-bipyridine). This catalysis represents a new avenue for using organosilanes in the catalytic C-H functionalization chemistry. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：2202 / 2205
页数：4
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