Properties of poly(n-butyl methacrylate) prepared by reverse atom transfer radical polymerization in an aqueous dispersed system

被引：12
|
作者：
Peng, H
Cheng, SY [1 ]
Feng, LX
机构：
[1] Hubei Univ, Sch Chem & Mat Sci, Wuhan 430062, Peoples R China
[2] Zhejiang Univ, Inst Polymer Sci & Engn, Hangzhou 310027, Peoples R China
来源：
JOURNAL OF APPLIED POLYMER SCIENCE | 2003年 / 89卷 / 06期
关键词：
atom transfer radical polymerization; emulsion polymerization; morphology; nucleation;
D O I：
10.1002/app.12256
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
Reverse atom transfer radical polymerization (ATRP) of n-butyl methacrylate (BMA) in waterborne media using Cu(II) complexes with azo initiators (i.e., reverse ATRP) was conducted. The influence of several factors, such as surfactant, catalyst, and reaction time, on the stability of the emulsion, the particle size, the morphology of the emulsion particles, and the control of the polymerization was investigated. The results showed great differences between ATRP and conventional emulsion polymerization, especially the nucleation mechanism and the kinetics. (C) 2003 Wiley Periodicals, Inc.
引用
收藏
页码：1542 / 1547
页数：6
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