CO2-induced amidobromination of olefins with bromamine-T

被引：17
|
作者：
Hayakawa, Junpei [1 ]
Kuzuhara, Mitsuhiro [1 ]
Minakata, Satoshi [1 ]
机构：
[1] Osaka Univ, Dept Appl Chem, Grad Sch Engn, Suita, Osaka 5650871, Japan
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 06期
关键词：
DIETHYL N; N-DIBROMOPHOSPHOROAMIDATE DBPA; BUTYL N; N-DIBROMOCARBAMATE BBC; BROMINE SOURCES; IONIC ADDITION; STEREOSELECTIVE AMINOBROMINATION; ALPHA; BETA-UNSATURATED KETONES; TERMINAL ALKENES; NITROGEN; NBS; N; N-DIHALOPHOSPHORAMIDES;
D O I：
10.1039/b923253m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The carbon dioxide (CO2)-induced amidobromination of olefins with bromamine-T is described. The method can be used in reactions with a wide range of olefins, both aromatic and aliphatic, as well as electron-rich and deficient olefins, leading to the regioselective formation of amidobrominated compounds.
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页码：1424 / 1430
页数：7
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