Impact of catalytic oil palm fronds (OPF) pulping on organosolv lignin properties

被引：28
|
作者：
Hussin, M. Hazwan [1 ,2 ]
Rahim, Afidah Abdul [1 ]
Ibrahim, Mohamad Nasir Mohamad [1 ]
Perrin, Dominique [2 ]
Yemloul, Mehdi [3 ]
Brosse, Nicolas [2 ]
机构：
[1] Univ Sains Malaysia, Sch Chem Sci, Lignocellulos Res Grp, Minden 11800, Penang, Malaysia
[2] Univ Lorraine, Fac Sci & Tech, Lab Etud & Rech MAt Bois LERMAB, F-54500 Vandoeuvre Les Nancy, France
[3] Aix Marseille Univ, Inst Sci Mol Marseille, Serv 512, F-13397 Marseille, France
来源：
POLYMER DEGRADATION AND STABILITY | 2014年 / 109卷
关键词：
Organosolv lignin; Oil palm fronds; 1,8-Dihydroxyanthraquinone; Phenolic; -OH; Antioxidant; PHYSICOCHEMICAL CHARACTERIZATION; ANTIOXIDANT PROPERTIES; AUTOHYDROLYSIS; ANTHRAQUINONE; CAPACITY;
D O I：
10.1016/j.polymdegradstab.2014.06.016
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
This article sheds light on the structural characteristic and antioxidant activity of the ethanol organosolv lignin extracted from oil palm fronds (OPF) via incorporation of 1,8-dihydroxyanthraquinone during the delignification process. The resulting modified organosolv lignin (DEOL) was studied by P-31 NMR, HSQC, HMBC and GPC. It was proposed that addition of a catalytic amount of 1,8-dihydroxyanthraquinone during pulping process; (1) enhanced the dissolution of lignin and the delignification rate, (2) improved the solubility of the resulting modified lignin (DEOL) by reducing its hydrophobicity properties and (3) improved its antioxidant activity compared to untreated organosolv lignin (EOL) (DEOL: 78% and EOL: 53% of Oxygen Uptake Inhibition (OUI) respectively). It was shown that antioxidant activity was closely related to its average molecular weight and phenolic hydroxyl content. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：33 / 39
页数：7
相关论文
共 50 条
  • [41] INFLUENCES OF THE OPERATING VARIABLES OF ACETOSOLV PULPING ON PULP PROPERTIES OF OIL PALM FROND FIBRES
    Wanrosli, W. D.
    Mazlan, I.
    Law, K. N.
    Nasrullah, R.
    MADERAS-CIENCIA Y TECNOLOGIA, 2011, 13 (02): : 193 - 202
  • [42] Effect of fiber loading on mechanical properties of oil palm frond/urea formaldehyde (OPF/UF) composite
    Richard, Beatrice Dimah
    Wahi, Azizah
    Nani, Rozie
    Iling, Elisha
    Osman, Shahril
    Ali, Dayang Siti Hazimmah
    INTERNATIONAL JOURNAL OF INTEGRATED ENGINEERING, 2019, 11 (07): : 122 - 128
  • [43] Agricultural palm oil tree residues as raw material for cellulose, lignin and hemicelluloses production by ethylene glycol pulping process
    Gonzalez Alriols, M.
    Tejado, A.
    Blanco, M.
    Mondragon, I.
    Labidi, J.
    CHEMICAL ENGINEERING JOURNAL, 2009, 148 (01) : 106 - 114
  • [44] Preparation and characterizations of oil palm fronds cellulose nanocrystal (OPF-CNC) as reinforcing filler in epoxy-Zn rich coating for mild steel corrosion protection
    Azani, Nur Fatin Silmi Mohd
    Haafiz, M. K. Mohamad
    Zahari, Azeana
    Poinsignon, Sophie
    Brosse, Nicolas
    Hussin, M. Hazwan
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2020, 153 : 385 - 398
  • [45] Palm: Production, composition, properties and nutritional impact of oil
    Morin, Odile
    OCL-OILSEEDS AND FATS CROPS AND LIPIDS, 2013, 20 (03) : 131 - 132
  • [46] Effect of Pd/C Catalytic Extraction on the Hydrothermal Depolymerization Properties of Ethanol Organosolv Lignin (EOL) in Supercritical Ethanol
    Zhou, Yuran
    Bin Wen
    Liu, Bei
    BIORESOURCES, 2023, 18 (03) : 4567 - 4579
  • [47] Production of oil palm (Elaeis guineensis) fronds lignin-derived non-toxic aldehyde for eco-friendly wood adhesive
    Hussin, M. Hazwan
    Samad, Noraini Abdul
    Abd Latif, Nur Hanis
    Rozuli, Nurul Adilla
    Yusoff, Siti Baidurah
    Gambier, Francois
    Brosse, Nicolas
    INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES, 2018, 113 : 1266 - 1272
  • [48] Pyro-catalytic deoxgenated bio-oil from palm oil empty fruit bunch and fronds with boric oxide in a fixed-bed reactor
    Lim, Xiao Y.
    Andresen, John M.
    FUEL PROCESSING TECHNOLOGY, 2011, 92 (09) : 1796 - 1804
  • [49] Impact of Carbon Dioxide Nanobubbles on Crystallising Properties of Palm Oil
    Khanh Phan
    Tuyen Truong
    Wang, Yong
    Bhandari, Bhesh
    FOOD AND BIOPROCESS TECHNOLOGY, 2024, 17 (11) : 4290 - 4302
  • [50] Impact of different inclusion levels of oil palm (Elaeis guineensis Jacq.) fronds on fatty acid profiles of goat muscles
    Ebrahimi, M.
    Rajion, M. A.
    Goh, Y. M.
    Sazili, A. Q.
    JOURNAL OF ANIMAL PHYSIOLOGY AND ANIMAL NUTRITION, 2012, 96 (06) : 962 - 969
12345