Synthesis, crystal structure and electrical conductivity of (bmim)[Pd(dmit)2)]2 (bmim=1-butyl-3-methylimidazolium, dmit=1,3-dithiol-2-thiol-2-thione-4,5-dithiolate)

被引：1

作者：

Jia, CY ^{[1
]}

Zhang, DQ ^{[1
]}

Xu, W ^{[1
]}

Shao, XF ^{[1
]}

Zhu, DB ^{[1
]}

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Organ Solids Lab, Beijing 100080, Peoples R China

来源：

SYNTHETIC METALS | 2003年 / 137卷 / 1-3期

关键词：

organic conductor; electrocrystalization;

D O I：

10.1016/S0379-6779(02)01085-8

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The synthesis, structural characterization, and electrical conductivity studies of charge-transfer compound (bmim)[Pd(dmit)(2)](2) was described. This compound was obtained as small needles by electrocrystalization of (bmim)(2)[Pd(dmit)(2)]. Crystallographic parmeters for C20H18N2S20Pd2: monoclinic system; space group: C2/c ; a = 6.3718 (13), b = 14.543 (3), c = 36.339 (7) Angstrom; a = 90, beta = 92.04 (3), gamma = 90; Z = 4, R = 0.0785 (I>2 degrees a (I)). The room temperature conductivity of this salt is 1.2 S . cm(-1), and it shows metallic conducting state in the temperature range of 287-245 K.

引用

页码：1345 / 1346

页数：2

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