Fitting the heat capacity for spin crossover systems

被引：2
|
作者：
Papánková, B [1 ]
Simon, P [1 ]
Boca, R [1 ]
机构：
[1] Slovak Univ Technol Bratislava, Dept Inorgan Chem, SK-81237 Bratislava, Slovakia
来源：
SOLID STATE CHEMISTRY V | 2003年 / 90-91卷
关键词：
Fe(II) complexes; spin crossover; heat capacity;
D O I：
10.4028/www.scientific.net/SSP.90-91.177
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
A series of Fe(II) complexes exhibiting the spin crossover with a different extent of the solid-state cooperativeness has been subjected to theoretical analysis. The experimental data on the heat capacity have been directly fitted by considering two models of the spin crossover: with an explicit vibrational partition function, or an effective degeneracy ratio.
引用
收藏
页码：177 / 181
页数：5
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