New bis-macrocyclic complexes with transition metal ions

被引：26

作者：

Singh, AK ^{[1
]}

Panwar, A ^{[1
]}

Singh, R ^{[1
]}

Baniwal, S ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Roorkee 247667, Uttar Pradesh, India

来源：

TRANSITION METAL CHEMISTRY | 2003年 / 28卷 / 02期

关键词：

D O I：

10.1023/A:1022916620211

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Template condensation of benzidine, formaldehyde, ethylenediamine or 1,3-diaminopropane, metal salt and 1-phenyl-1,3-butanedione or 2,3-butanedione in a 1:4:2:2 molar ratio results in the formation of two new series of binuclear pentaaza macrocyclic complexes: dichloro[1,1'-phenylbis(7-methyl-9-phenyl-1,3,6,10,13-pentaazacyclotetradeca-6,9-diene) metal(II)], [M2LCl4] (M = Co-II, Cu-II, Fe-III and Zn-II) and dichloro[1,1'-phenylbis(8,9-dimethyl-1,3,7,10,14-pentaazacyclopentadeca-7,9-diene) metal(II)], [M2L'Cl-4] (M = Ni-II, Co-II, Cu-II and Cd-II). Both series were characterized by i.r., H-1-n.m.r., u.v.-vis. spectral studies, conductivity and magnetic susceptibility measurements.

引用

页码：160 / 162

页数：3

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