Outer-sphere interactions between octahedral chiral cobalt(III) complexes and water-soluble calixarenes

被引：10

作者：

Mustafina, AR

Skripacheva, VV

Gubskaya, VP

Gruner, M

Solv'eva, SE

Antipin, IS

Kazakova, EK

Konovalov, AI

Habicher, WD

机构：

[1] Tech Univ Dresden, Inst Organ Chem, D-01062 Dresden, Germany

[2] Kazan VI Lenin State Univ, Kazan 420008, Russia

[3] Russian Acad Sci, Kazan Res Ctr, AE Arbuzov Organ & Phys Chem Inst, Kazan 420088, Russia

来源：

RUSSIAN CHEMICAL BULLETIN | 2004年 / 53卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

sulfonate derivatives of thiacalix[4]arene and calix[4]resorcinarene; octahedral cobalt(III) complexes; outer-sphere association; structure; stability;

D O I：

10.1023/B:RUCB.0000046249.10018.db

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structures and stability of outer-sphere associates of sulfonate derivatives of thiacalix[4]arene and calix[4]resorcinarene with coordinatively saturated cobalt(III) bis- and tris-chelates ([Co(L-His)(2)](+), [Co(en)(2)ox](+), [Co(en)(3)](3+), and [Co(dipy)(3)](3+)) were compared based on the data from UV, CD, 1D H-1 NMR, and 2D (2D NOESY) H-1 NMR spectroscopy and conductometry. Outer-sphere association is accompanied by partial penetration of the chelate rings of the complexes into the hydrophobic cavity of calixarene, which induces changes in the spectroscopic and spectropolarimetric properties of the cobalt(III) complexes.

引用

页码：1511 / 1519

页数：9

共 50 条

[41] OUTER-SPHERE ELECTRON-TRANSFER REACTIONS OF MACROCYCLIC COMPLEXES OF COBALT(III) - CRITICAL ASSESSMENT OF LINEAR FREE-ENERGY RELATIONS
RILLEMA, DP
ENDICOTT, JF
PATEL, RC
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (02) : 394 - &
[42] OUTER-SPHERE COMPLEX FORMATION BETWEEN TRIS-(ETHYLENEDIAMINE)COBALT(III) ION AND IODIDE ION IN AQUEOUS-SOLUTION
JOHANSSON, L
ACTA CHEMICA SCANDINAVICA, 1971, 25 (10): : 3752 - +
[43] LINEAR FREE-ENERGY RELATIONSHIP FOR OUTER-SPHERE REDUCTION OF RUTHENIUM(III) AMINE COMPLEXES BY TITANIUM(III)
DAVIES, KM
EARLEY, JE
INORGANIC CHEMISTRY, 1978, 17 (12) : 3350 - 3354
[44] Synthesis and characterization of water-soluble, heteronuclear ruthenium(III)/ferrocene complexes and their interactions with biomolecules
Anderson, Craig M.
Jain, Swapan S.
Silber, Lisa
Chen, Kody
Guha, Sumedha
Zhang, Wancong
McLaughlin, Emily C.
Hu, Yongfeng
Tanski, Joseph M.
JOURNAL OF INORGANIC BIOCHEMISTRY, 2015, 145 : 41 - 50
[45] PREPARATIONS AND PROPERTIES OF SOME WATER-SOLUBLE COBALT(III)-POLY--4-VINYLPYRIDINE COMPLEXES
KURIMURA, Y
TSUCHIDA, E
KANEKO, M
JOURNAL OF POLYMER SCIENCE PART A-1-POLYMER CHEMISTRY, 1971, 9 (12): : 3511 - &
[46] INNER AND OUTER-SPHERE COMPLEXATION BETWEEN EUROPIUM(III) AND GLYCINE IN AQUEOUS-METHANOL
SILBER, HB
CAMPBELL, RL
NGUYEN, N
PARKER, T
SIBLEY, SP
JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 225 (1-2) : 291 - 294
[47] Outer-sphere complexation of Tris(2,2′-dipyridyl)cobalt(III) with hydrophosphate and dihydrophosphate anions
Zorina, NV
Pashkov, GL
Stupko, TV
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (04) : 585 - 588
[48] ADIABATIC INTRAMOLECULAR ELECTRON-TRANSFER IN PYRAZINE-2,6-DICARBOXYLATO-BRIDGED COMPLEXES OF COBALT(III)-RUTHENIUM(II) AND OF COBALT(III)-IRON(II) - COMPARISON OF INNER-SPHERE VS OUTER-SPHERE ACTIVATED COMPLEXES
NEVES, A
HERRMANN, W
WIEGHARDT, K
INORGANIC CHEMISTRY, 1984, 23 (22) : 3435 - 3443
[49] ELECTRON TRANSFER THROUGH ORGANIC STRUCTURAL UNITS .10. CATALYSIS, BY PYRIDINE DERIVATIVES, OF OUTER-SPHERE REDUCTIONS OF COBALT(III) - EVIDENCE FOR AN UNUSUALLY REACTIVE OUTER-SPHERE REDUCING AGENT
BARBER, JR
GOULD, ES
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1971, 93 (16) : 4045 - &
[50] Two novel chains based on capsules supported by water-soluble calixarenes and metal complexes
Xiong, Kecai
Jiang, Feilong
Wu, Mingyan
Gai, Yanli
Chen, Qihui
Zhang, Shuquan
Ma, Jie
Han, Dong
Hong, Maochun
JOURNAL OF SOLID STATE CHEMISTRY, 2012, 192 : 215 - 220

← 1 2 3 4 5 →