A crossed-beam study of the reaction C(1D)+H2(X1Σ+,υ=0)→CH(X2Π,υ′)+H(2S)

被引：66

作者：

Bergeat, A

Cartechini, L

Balucani, N

Capozza, G

Phillips, LF

Casavecchia, P ^{[1
]}

Volpi, GG

Bonnet, L

Rayez, JC

机构：

[1] Dipartimento Chim, I-06123 Perugia, Italy

[2] Univ Bordeaux 1, Lab Physicochim Mol, F-33405 Talence, France

[3] Univ Bordeaux 1, Dept Mesures Phys, IUT A, F-33405 Talence, France

来源：

CHEMICAL PHYSICS LETTERS | 2000年 / 327卷 / 3-4期

关键词：

D O I：

10.1016/S0009-2614(00)00870-8

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Product angular and time-of-flight distributions have been measured for the first time for the prototypical insertion reaction C(D-1) + H-2 using the crossed-beam technique with mass spectrometric detection at the collision energy of 1.86 kcal mol(-1). Center-of-mass angular and kinetic energy distributions have been derived for CH(X(2)Pi, nu', = 0) + H products and compared with those of statistical calculations based on phase-space theory. (C) 2000 Elsevier Science B.V. All rights reserved.

引用

页码：197 / 202

页数：6

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