I2O5-mediated bromohydroxylation and dibromination of olefins using KBr in water

被引：8
|
作者：
Wang, Yajun [1 ]
Wang, Jinxi [2 ]
Xiong, Yun [3 ]
Liu, Zhong-Quan [3 ]
机构：
[1] Lanzhou Univ Technol, Sch Civil Engn, Lanzhou 730050, Peoples R China
[2] Lanzhou Univ Arts & Sci, Sch Chem Engn, Lanzhou 730000, Peoples R China
[3] Lanzhou Univ, State Key Lab Appl Organ Chem, Lanzhou 730000, Gansu, Peoples R China
来源：
TETRAHEDRON LETTERS | 2014年 / 55卷 / 16期
基金：
美国国家科学基金会;
关键词：
Bromohydroxylation; Dibromination; Alkene; HYPERVALENT IODINE; METAL-FREE; EFFICIENT BROMINATION; N-BROMOSUCCINIMIDE; AROMATIC-COMPOUNDS; CARBONYL-COMPOUNDS; LITHIUM BROMIDE; ALKENES; ACID; HALOGENATION;
D O I：
10.1016/j.tetlet.2014.03.064
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient and green bromohydroxylation and dibromination of various olefins mediated by I2O5 has been developed in this work. A series of olefins gave the corresponding alpha-bromo-alcohols and dibromides as the major products using KBr as the brominating reagent in aqueous medium at room temperature. The diastereo- and regio-selectivities are extremely high. (C) 2014 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2734 / 2737
页数：4
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