Alkaline earth diazapentadienyl compounds:: Structure of [Ba2{(C6H11)NC(Me)CHC(Me)-N(C6H11)}3{(SiMe3)2N}]

被引：0
|
作者：
Clegg, W
Coles, SJ
Cope, EK
Mair, FS
机构：
[1] Univ Manchester, Inst Sci & Technol, Dept Chem, Manchester M60 1QD, Lancs, England
[2] Newcastle Univ, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England
[3] UCL Royal Inst Great Britain, Warrington WA4 4AD, Cheshire, England
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 1998年 / 37卷 / 06期
关键词：
barium; bridging ligands; chemical vapor deposition; coordination modes; N ligands;
D O I：
10.1002/(SICI)1521-3773(19980403)37:6<796::AID-ANIE796>3.0.CO;2-B
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Three different bonding modes in one molecule! The diazapentadienyl ligands in the title compound 1 adopt η1,η1-N,N-chelating plus η5-terminal, η1η1-N,N chelating plus η5-bridging, and novel η1-N plus η3-1-aza-allyl bonding modes. R = cyclohexyl.
引用
收藏
页码：796 / 798
页数：3
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