Electrostatic effects in films stabilised by non-ionic surfactants

被引:10
|
作者
Marquez-Beltran, Cesar [1 ]
Langevin, Dominique [1 ]
机构
[1] Univ Paris 11, Lab Phys Solides, F-91405 Orsay, France
关键词
thin liquid films; disjoining pressure; non-ionic surfactants;
D O I
10.1016/j.jcis.2006.10.015
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The disjoining pressure 17 of films of aqueous octyl-beta-glucoside (beta-C(8)G(1)) solutions with and without salt was measured as a function of the film thickness by means of a thin film pressure balance. The analysis of the experiments confirms the presence of an electrostatic double layer which dominates the long-range interactions as found in previous experiments with other non-ionic surfactants in the presence of added salt. In the absence of salt, we find a local ion concentration much higher than that of the residual ionic impurities present in the bulk solution. (c) 2006 Elsevier Inc. All rights reserved.
引用
收藏
页码:47 / 51
页数:5
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