Organo-directed synthesis of manganese vanadates with variable stoichiometry and dimensionality:: 1-D [(Hen)2Mn(VO3)4], 2-D [H2en]2[Mn(VO3)6], and 3-D [H2en] [MnF(VO3)3]

被引:43
|
作者
Law, TSC [1 ]
Williams, ID [1 ]
机构
[1] Hong Kong Univ Sci & Technol, Dept Chem, Kowloon, Hong Kong, Peoples R China
关键词
D O I
10.1021/cm000190c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
View of the open framework of the [H2en][MnF-(VO3)3] one of a new family of organically templated manganese vanadates synthesized under mild conditions. The compound shown here has novel hexavanadate rings connecting manganese fluoride pillars and forming micro-channels which contain the organic counterions.
引用
收藏
页码:2070 / 2072
页数:3
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