(η2-Tetracyanoethene)bis(triphenylphosphine-κP)palladium-dichloromethane (1/0.7)

被引：0
|
作者：
Shackleton, Z [1 ]
Kilner, CA [1 ]
Reid, GD [1 ]
Halcrow, MA [1 ]
机构：
[1] Univ Leeds, Dept Chem, Leeds LS2 9JT, W Yorkshire, England
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 2003年 / 59卷
关键词：
D O I：
10.1107/S010827010300458X
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The title compound, [Pd(C6N4)(C18H15P)(2)].0.7CH(2)Cl(2), shows a planar coordination geometry around the metal atom that is an almost perfect isosceles triangle if the tetracyanoethene (tcne) ligand is deemed to occupy a single coordination site. The framework of the tcne ligand shows small distortions due to intramolecular steric contacts between the C=N groups and phenyl rings of the triphenylphosphine ligands.
引用
收藏
页码：M136 / M138
页数：3
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