Adsorption/desorption of the explosive tetryl in peat and yellow-red argissol

被引：25

作者：

Falone, SZ ^{[1
]}

Vieira, EM ^{[1
]}

机构：

[1] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil

来源：

QUIMICA NOVA | 2004年 / 27卷 / 06期

关键词：

explosive; adsorption; desorption;

D O I：

10.1590/S0100-40422004000600002

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

This paper presents the study of adsorption/desorption of the explosive tetryl (2,4,6-trinitrophenylmethyl-nitramine) in different matrices, such as in natura soil, roasted soil, humic acid of soil, in natura peat, roasted peat and humic acid of peat. The aim of the study is to evaluate the interaction capacity of those matrices with the explosive. The analytic technique used was HPLC (high performance liquid chromatography), with UV-detection at 230 nm. The Freundlich isotherms were utilized for the mathematical treatment of the data. The results indicated that in natura soil and in natura peat (with organic substances) are excellent matrices for the retention of tetryl, adsorbing it and keeping it immovable, preventing it front contaminating the groundwater. The largest adsorption of the explosive ocurred in in natura soil, while the smallest desorption was observed in in natura peat. After the calcination of the matrices, the smallest adsorption was observed, indicating that the retention occurs in the organic substance.

引用

页码：849 / 854

页数：6

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