Activation of hydrogen- and halogen-bonding interactions in tetrathiafulvalene-based crystalline molecular conductors

被引：515

作者：

Fourmigué, M ^{[1
]}

Batail, P ^{[1
]}

机构：

[1] Univ Angers, UMR 6200 CNRS, UFR Sci, Lab Chim Ingn Mol & Mat CIMMA, F-49045 Angers, France

来源：

CHEMICAL REVIEWS | 2004年 / 104卷 / 11期

关键词：

D O I：

10.1021/cr030645s

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview is given of the effort accomplished to direct intermolecular interactions in crystalline molecular conductors based on tetrathiafulvalene (TTF) derivatives. Focus is on the use of directional, electrostatic, normal, and weak hydrogen bonds and halogen bonds. Specifically, tetrathiafulvalene molecules functionalized by hydrogen-bonding donor or acceptor groups such as alcohols, carboxylic acids, and amides as well as halogenated tetrathiafulvalenes and their salts, are covered, specifically concentrating on the crystal structures they adopt in the solid state.

引用

页码：5379 / 5418

页数：40

共 44 条

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