Continuous flow purification of nanocrystal quantum dots

被引:16
|
作者
Kim, Duckjong [1 ,2 ]
Park, Hye Kyung [1 ]
Choi, Hyekyoung [1 ,2 ]
Noh, Jaehong [1 ]
Kim, Kyungnam [1 ]
Jeong, Sohee [1 ,2 ]
机构
[1] KIMM, Dept Nano Mech, Taejon 305343, South Korea
[2] Korea Univ Sci & Technol UST, Taejon 305350, South Korea
基金
新加坡国家研究基金会;
关键词
NUCLEATION; EXCHANGE; LIGANDS; OLEATE; FILMS; PBSE;
D O I
10.1039/c4nr04351k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Colloidal quantum dot (QD) purification is typically conducted via repeating precipitation-redispersion involving massive amounts of organic solvents and has been the main obstacle in mass production of QDs with dependable surface properties. Our results show that the electric field apparently affects the streamlining of QDs and that we could continuously collect stably dispersed QDs by the electrophoretic purification process. The purification yield increases as the electric potential difference increases or the flow rate decreases, but reaches an asymptotic value. The yield can be further improved by raising the absolute magnitude of the mobility of QDs with the addition of solvents with high dielectric constants. The continuous purification process sheds light on industrial production of colloidal nanomaterials.
引用
收藏
页码:14467 / 14472
页数:6
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