Continuous flow purification of nanocrystal quantum dots

被引:16
|
作者
Kim, Duckjong [1 ,2 ]
Park, Hye Kyung [1 ]
Choi, Hyekyoung [1 ,2 ]
Noh, Jaehong [1 ]
Kim, Kyungnam [1 ]
Jeong, Sohee [1 ,2 ]
机构
[1] KIMM, Dept Nano Mech, Taejon 305343, South Korea
[2] Korea Univ Sci & Technol UST, Taejon 305350, South Korea
基金
新加坡国家研究基金会;
关键词
NUCLEATION; EXCHANGE; LIGANDS; OLEATE; FILMS; PBSE;
D O I
10.1039/c4nr04351k
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Colloidal quantum dot (QD) purification is typically conducted via repeating precipitation-redispersion involving massive amounts of organic solvents and has been the main obstacle in mass production of QDs with dependable surface properties. Our results show that the electric field apparently affects the streamlining of QDs and that we could continuously collect stably dispersed QDs by the electrophoretic purification process. The purification yield increases as the electric potential difference increases or the flow rate decreases, but reaches an asymptotic value. The yield can be further improved by raising the absolute magnitude of the mobility of QDs with the addition of solvents with high dielectric constants. The continuous purification process sheds light on industrial production of colloidal nanomaterials.
引用
收藏
页码:14467 / 14472
页数:6
相关论文
共 50 条
  • [1] Electrochromic nanocrystal quantum dots
    Wang, CJ
    Shim, M
    Guyot-Sionnest, P
    SCIENCE, 2001, 291 (5512) : 2390 - 2392
  • [2] NANOCRYSTAL QUANTUM DOTS FOR QUANTUM INFORMATION PROCESSING
    Littleton, Brad
    BIOPHOTONICS: SPECTROSCOPY, IMAGING, SENSING, AND MANIPULATION, 2011, : 379 - 379
  • [3] Continuous Purification of Colloidal Quantum Dots in Large-Scale Using Porous Electrodes in Flow Channel
    Hosub Lim
    Ju Young Woo
    Doh C. Lee
    Jinkee Lee
    Sohee Jeong
    Duckjong Kim
    Scientific Reports, 7
  • [4] Continuous Purification of Colloidal Quantum Dots in Large-Scale Using Porous Electrodes in Flow Channel
    Lim, Hosub
    Woo, Ju Young
    Lee, Doh C.
    Lee, Jinkee
    Jeong, Sohee
    Kim, Duckjong
    SCIENTIFIC REPORTS, 2017, 7
  • [5] Continuous hydrothermal flow synthesis of graphene quantum dots
    Kellici, Suela
    Acord, John
    Moore, Katherine E.
    Power, Nicholas P.
    Middelkoop, Vesna
    Morgan, David J.
    Heil, Tobias
    Coppo, Paolo
    Baragau, Ioan-Alexandru
    Raston, Colin L.
    REACTION CHEMISTRY & ENGINEERING, 2018, 3 (06): : 949 - 958
  • [6] Nanocrystal quantum dots: From single dots to lasing dots.
    Bawendi, MG
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2002, 224 : U651 - U651
  • [7] Lifetime blinking in nonblinking nanocrystal quantum dots
    Christophe Galland
    Yagnaseni Ghosh
    Andrea Steinbrück
    Jennifer A. Hollingsworth
    Han Htoon
    Victor I. Klimov
    Nature Communications, 3
  • [8] Electroabsorption spectra of PbSe nanocrystal quantum dots
    Liu, Xiaoming
    Iimori, Toshifumi
    Ohshima, Ruriko
    Nakabayashi, Takakazu
    Ohta, Nobuhiro
    APPLIED PHYSICS LETTERS, 2011, 98 (16)
  • [9] Stimulated emission and lasing in nanocrystal quantum dots
    Klimov, VI
    Mikhailovsky, AA
    Hollingsworth, JA
    Malko, A
    Leatherdale, CA
    Eisler, HJ
    Bawendi, MG
    QUANTUM CONFINEMENT VI: NANOSTRUCTURED MATERIALS AND DEVICES, 2001, 2001 (19): : 321 - 333
  • [10] Exchange interaction in InAs nanocrystal quantum dots
    Banin, U
    Lee, JC
    Guzelian, AA
    Kadavanich, AV
    Alivisatos, AP
    SUPERLATTICES AND MICROSTRUCTURES, 1997, 22 (04) : 559 - 567