H2N(CH2)2NH3+.[Mn{H2N(CH2)2NH2}3]2+.-[SbSe4]3-

被引：20
|
作者：
Wendland, F [1 ]
Nather, C [1 ]
Schur, M [1 ]
Bensch, W [1 ]
机构：
[1] Univ Kiel, Inst Anorgan Chem, D-24089 Kiel, Germany
来源：
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1998年 / 54卷
关键词：
D O I：
10.1107/S0108270197014030
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reaction of elemental manganese, antimony and selenium with 1,2-ethanediamine (en) in an aqueous ethaneamine solution under hydrothermal conditions yields orange crystals of 2-aminoethylammonium tris(1,2-ethanediamine)manganese tetraselenoantimonate, enH.Mn(en)(3).SbSe4. The structure contains tetrahedral SbSe43- anions and octahedral Mn(en)(3)(2+) cations, as well as monoprotonated ethanediamine molecules.
引用
收藏
页码：317 / 319
页数：3
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