Reduced species (HSO2-,SO2•-) promoted one-pot efficient synthesis of phenyl alkyl selenides

被引：4

作者：

Tang Ri-Yuan ^{[1
]}

Zhong Ping ^{[1
]}

Lin Qiu-Lian ^{[1
]}

机构：

[1] Wenzhou Univ, Sch Chem & Mat Sci, Wenzhou 325027, Zhejiang, Peoples R China

来源：

CHINESE JOURNAL OF CHEMISTRY | 2007年 / 25卷 / 04期

关键词：

diselenide; selenide; rongalite; sodium dithionite; one-pot; UNSYMMETRICAL DIORGANYL SELENIDES; DIRECT PERFLUOROALKYLATION; DIPHENYL DISELENIDE; MEDIATED CLEAVAGE; SODIUM; REDUCTION; SULFIDES; HALIDES; DISULFIDES; IODIDE;

D O I：

10.1002/cjoc.200790104

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Reduced species (HSO2-, SO2.-) promoted one-pot synthesis of phenyl alkyl selenides has been developed. This synthetic method was achieved by reactions of diphenyl diselenide with alkyl halides at room temperature. It is noteworthy that the reactions were operated under mild reaction conditions, required short time, and got good results. A single electron transfer reaction mechanism was proposed for the reaction.

引用

页码：558 / 561

页数：4

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