Selective removal of cesium and strontium using porous frameworks from high level nuclear waste

被引：161

作者：

Aguila, Briana ^{[1
,2
]}

Banerjee, Debasis ^{[1
]}

Nie, Zimin ^{[3
]}

Shin, Yongsoon ^{[1
]}

Ma, Shengqian ^{[2
]}

Thallapally, Praveen K. ^{[1
]}

机构：

[1] Pacific NW Natl Lab, Phys & Computat Sci Directorate, Richland, WA 99354 USA

[2] Univ S Florida, Dept Chem, Tampa, FL 33620 USA

[3] Pacific NW Natl Lab, Energy & Environm Directorate, Richland, WA 99354 USA

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 35期

关键词：

METAL-ORGANIC FRAMEWORKS; RESIN; WATER; CS;

D O I：

10.1039/c6cc00843g

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficient and cost-effective removal of radioactive Cs-137 and Sr-90 found in spent fuel is an important step for safe, long-term storage of nuclear waste. Solid-state materials such as resins and titanosilicate zeolites have been assessed for the removal of Cs and Sr from aqueous solutions, but there is room for improvement in terms of capacity and selectivity. Herein, we report the Cs+ and Sr2+ exchange potential of an ultra stable MOF, namely, MIL-101-SO3H, as a function of different contact times, concentrations, pH levels, and in the presence of competing ions. Our preliminary results suggest that MOFs with suitable ion exchange groups can be promising alternate materials for cesium and strontium removal.

引用

页码：5940 / 5942

页数：3

共 50 条

[21] Novel polymer inclusion membrane containing a macrocyclic ionophore for selective removal of strontium from nuclear waste solution
Mohapatra, PK
Pathak, PN
Kelkar, A
Manchanda, VK
NEW JOURNAL OF CHEMISTRY, 2004, 28 (08) : 1004 - 1009
[22] Phytoremediation of 137cesium and 90strontium from solutions and low-level nuclear waste by Vetiveria zizanoides
Singh, Shraddha
Eapen, Susan
Thorat, Vidya
Kaushik, C. P.
Raj, Kanwar
D'Souza, S. F.
ECOTOXICOLOGY AND ENVIRONMENTAL SAFETY, 2008, 69 (02) : 306 - 311
[23] Removal of Cesium from Radioactive Waste Liquids Using Geomaterials
Zhang, Haixin
Zhu, Mingze
Du, Xiaoyu
Feng, Sihan
Miyamoto, Naoto
Kano, Naoki
APPLIED SCIENCES-BASEL, 2021, 11 (18):
[24] Separation of radioactive cesium from nuclear waste solutionsSeparation of radioactive cesium from nuclear waste solutions
Radioaktllvisen cesiumin erotus ydinjaeteliunksista
1600, (21):
[25] Strontium and actinide separations from high level nuclear waste solutions using monosodium titanate 1. Simulant testing
Hobbs, DT
Barnes, MJ
Pulmano, RL
Marshall, KM
Edwards, TB
Bronikowski, MG
Fink, SD
SEPARATION SCIENCE AND TECHNOLOGY, 2005, 40 (15) : 3093 - 3111
[26] Adsorptive removal of cobalt, strontium and cesium using AMP-PAN in laundry wastewater from nuclear power plant
Park, Yeon-Jin
Lee, Young-Chae
Shin, Won Sik
Choi, Sang-June
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 237
[27] Selective removal of radionuclides from nuclear waste effluents using inorganic ion exchangers
Koivula, Risto
Harjula, Risto
Lehto, Jukka
COMBINED AND HYBRID ADSORBENTS: FUNDAMENTALS AND APPLICATIONS, 2006, : 37 - +
[28] Fixed-bed column for the removal of cesium, strontium, and lead ions from aqueous solutions using brick kiln waste
Metwally, Sayed S.
El-Sherief, Eman A.
Mekhamer, Hameda S.
SEPARATION SCIENCE AND TECHNOLOGY, 2020, 55 (04) : 635 - 647
[29] Electrochemical Removal of Radioactive Cesium from Nuclear Waste Using the Dendritic Copper Hexacyanoferrate/Carbon Nanotube Hybrids
Zheng, Yuanyuan
Qiao, Junhua
Yuan, Junhua
Shen, Jianfeng
Wang, Ai-jun
Niu, Li
ELECTROCHIMICA ACTA, 2017, 257 : 172 - 180
[30] Study on selective separation of cesium from high level liquid waste using a macroporous silica-based supramolecular recognition absorbent
Wu, Y.
Kim, S. -Y.
Tozawa, D.
Ito, T.
Tada, T.
Hitomi, K.
Kuraoka, E.
Yamazaki, H.
Ishii, K.
JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2012, 293 (01) : 13 - 20

← 1 2 3 4 5 →